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21:00 – Dienstag 23 November, 2021
Barcelona – Benfica
- Ausgestrahlt auf
- DAZN
Spielende (0 - 0)
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| 90' |  | Adel Taarabt |
| 90' | | Odisseas Vlachodimos |
Sergino Dest Clément Lenglet |  | 86' |
Eric García Martret Ronald Federico Araújo da Silva | | 86' |
| 81' | | Haris Seferović Alejandro Grimaldo García |
| 70' | | Valentino Lazaro Rafael Alexandre Fernandes Ferreira da Silva |
| 70' | | Luís Miguel Afonso Fernandes Everton Sousa Soares |
Ousmane Dembélé Yusuf Demir | | 66' |
| 59' | | Adel Taarabt João Mário Naval da Costa Eduardo |
| 59' | | Darwin Gabriel Núñez Ribeiro Roman Yaremchuk |
| Gerard Piqué Bernabéu | | 49' |
| 49' | | João Mário Naval da Costa Eduardo |
| Halbzeitpause 0-0 | ||
| 36' | | Alejandro Grimaldo García |
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